A first step of a calibration and understanding the functioning of the spectrometer is a measurement with X-rays of well understood line shape in the preparatory state of the experiment. Fluorescence X-rays are not useful for this purpose as their line shape is rather complicated because of satellite structures. Also their natural width is much broader than the resolution of the available crystals. X-ray transitions of one-electron atoms are better suited as their energies are known with a precision of typically in the energy region of interest. The line shape is also influenced by Doppler broadening depending on the temperature which is needed to ionize the atoms in the ECR source. A Maxwellian distribution of the velocities in the ECR plasma results in a Gaussian lineshape of the X-ray lines. The temperature (energy) of the ions in the ECR plasma is not a priori known and depends on the magnetic field geometry of the ECR source as well as on the high frequency parameters. A value between and per charge value is most probable [80]. For the following estimate a value of per charge unit is assumed. The Doppler width is expected to be a factor of 20 higher than the natural line width for the small Z and almost a factor of 10 higher for the higher Z. This is much more favorable than the conditions with fluorescence lines. The intensity of emitted X-rays is expected to be high enough to do calibration measurements in a time much shorter (less than one hour) compared to measurements with exotic atoms which last typically some days per measured energy. It is therefore planned to set up an ECR source and do calibration measurements well before the real measurement with pions and muons [81]. These calibration measurements will start with a diagnosis of the ECR source using survey measurements with CCD detectors and then continue with a high resolution X-ray spectroscopy with crystals. In this way yield and Doppler width of the ECR source will be determined. In a final step the two-crystal set-up with crystals will be tested. In Table 7 some characteristics of one-electron lines and of fluorescence lines relevant for the required energy region are shown. At first it can be stated that no line really coincides with a muonic or pionic hydrogen transition. It can however be noted that the energies of the transitions from the one-electron atom of nuclear charge Z almost coincide with the fluorescence lines of Z+1 as one electron almost shields one nuclear charge. This offers the possibility to determine the peak positions of the fluorescence lines during the calibration measurement with precision. This more technical fact may be of help during the real measurements to check the angular precision of the spectrometer as fluorescence lines are readily available.
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